Man, those later model wiring diagrams are a pain in the ass to follow. They jump all over the place. Anyway I think this is the way the circuit operates:
Out of the fuse block on ECMB, into the giant common pink/black circuit and then into the brake override switch. Out of the brake switch (as a purple) and through the diode set.
The function of the diode set as pertains to the TCC is that it disables the TCC if the front axle is engaged.
The purple comes out of the diode array as a purple/white and transits the firewall at the bulkhead connetor. It stays purple/white all the way to the + side of the TCC coil.
Coming out of the - side of the coil it is tan/black. Goes from the TCC coil to the control module. The control module grounds the tan/black internally - when the operating permissives are met - and the TCC pulls in.
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If you are sure that the brake switch is good, I would jump the 420 (purple) to the 820 (purple/white). If you then have power at the positive side of the TCC coil, you have pretty much narrowed it down to either a bad diode array or a faulty front axle switch in the transfer case.